Section: Machining
Machining

Tool Materials

Quick Cheat Sheet

Summary

Cutting tool materials must combine hardness (especially HOT hardness), toughness, wear resistance and chemical stability. Selection trades cost off against achievable cutting speed.

Key Points

  • Required properties: hot hardness, toughness, wear resistance, chemical stability, thermal-shock resistance
  • Material families: carbon steel → HSS → cast cobalt (Stellite) → cemented carbide → coated carbide → ceramics → CBN → diamond
  • HSS designation 18-4-1 = 18% W, 4% Cr, 1% V (plus 0.7% C)
  • Cemented carbide = WC particles in a cobalt binder; coatings (TiN, TiC, Al₂O₃) extend life
  • Ceramics for high-speed finishing of cast iron and hardened steel
  • CBN for hardened steels; PCD (diamond) for non-ferrous and composites only

Remember This

  • 1Hardness order: Diamond > CBN > Ceramic > Carbide > Cast cobalt > HSS > Carbon steel
  • 2Toughness order is the REVERSE of hardness order
  • 3Diamond reacts with iron at high T (graphitisation) → never use on ferrous
  • 4TiN coating is gold; Al₂O₃ coating is grey (high T, high V)
  • 5Carbon steel tool loses hardness above ~250 °C — useless for modern machining

Requirements for Cutting Tool Materials

  1. Hardness - Must be harder than work material (hot hardness important)
  2. Toughness - Ability to absorb energy without fracturing
  3. Wear Resistance - Resist abrasion and adhesion
  4. Hot Hardness - Retain hardness at elevated temperatures
  5. Chemical Stability - Resist chemical reactions with work material

Types of Tool Materials

1. High Speed Steel (HSS)

Composition: Iron-based alloy with tungsten (W), chromium (Cr), vanadium (V), and sometimes cobalt (Co)

Properties:

  • Good toughness
  • Can be hardened to high hardness (Rc 60-65)
  • Retains hardness up to 500-600°C
  • Easy to fabricate and grind
  • Lower cost

Types:

  • M-series (Molybdenum type): 6% W, 5% Mo, 4% Cr, 2% V
  • T-series (Tungsten type): 18% W, 4% Cr, 1% V

Applications: Drills, taps, reamers, milling cutters, general purpose tools

Cutting Speed: 10-60 m/min

2. Cemented Carbides

Composition: Tungsten carbide (WC) particles bonded with cobalt (Co) binder

Properties:

  • Very hard (Rc 70-80)
  • High hot hardness (up to 1000°C)
  • High wear resistance
  • Brittle (low toughness)
  • More expensive than HSS

Types:

  • Straight WC-Co - For cast iron, non-ferrous metals
  • WC-TiC-Co - For steel machining
  • WC-TiC-TaC-Co - For difficult-to-machine materials

Grades:

  • C-1 to C-4 - Increasing toughness, decreasing hardness (roughing to finishing)
  • Higher cobalt % → more toughness, less hardness

Applications: High-speed machining, mass production, CNC operations

Cutting Speed: 100-400 m/min

3. Coated Carbides

Base: Cemented carbide substrate with thin coating (2-10 μm)

Coating Materials:

  • TiC (Titanium Carbide) - Wear resistance
  • TiN (Titanium Nitride) - Low friction, oxidation resistance
  • Al₂O₃ (Aluminum Oxide) - Chemical stability, heat resistance

Advantages:

  • Combines hardness of coating with toughness of substrate
  • Higher cutting speeds (20-50% more than uncoated)
  • Longer tool life (2-10 times)
  • Better surface finish

Coating Methods:

  • CVD (Chemical Vapor Deposition) - 900-1050°C
  • PVD (Physical Vapor Deposition) - 450-600°C

4. Ceramics

Composition: Primarily aluminum oxide (Al₂O₃) or silicon nitride (Si₃N₄)

Properties:

  • Extremely hard
  • Excellent hot hardness (up to 1200°C)
  • Very brittle
  • Low thermal conductivity
  • Chemically inert

Types:

  • Oxide ceramics (Al₂O₃) - White/black ceramics
  • Silicon nitride (Si₃N₄) - Better toughness

Applications: High-speed finishing of cast iron and hardened steel

Cutting Speed: 300-2000 m/min

Limitations: Cannot handle interrupted cuts, require rigid setup

5. Cubic Boron Nitride (CBN)

Properties:

  • Second hardest material after diamond
  • Excellent hot hardness
  • Chemically inert to ferrous metals
  • Good thermal conductivity

Applications:

  • Hardened steels (Rc 45-65)
  • Hard cast irons
  • Superalloys
  • Finishing operations

Cutting Speed: 200-500 m/min

Form: CBN particles bonded to carbide substrate

6. Diamond

Types:

  • Single crystal diamond - Natural
  • Polycrystalline diamond (PCD) - Synthetic, bonded to carbide

Properties:

  • Hardest material
  • Excellent wear resistance
  • High thermal conductivity
  • Chemically reacts with ferrous metals at high temperatures

Applications:

  • Non-ferrous metals (aluminum, copper, brass)
  • Non-metallic materials (plastics, composites, graphite)
  • Ultra-precision machining

Limitations: Cannot machine steel or cast iron (chemical affinity with carbon)

Cutting Speed: 500-3000 m/min

Tool Material Selection Guide

Material Hardness Toughness Hot Hardness Cost Typical Speed
HSS Medium High Low Low 10-60 m/min
Carbide High Medium High Medium 100-400 m/min
Coated Carbide High Medium High Medium 150-500 m/min
Ceramic Very High Low Very High High 300-2000 m/min
CBN Very High Low Very High Very High 200-500 m/min
Diamond Highest Low High* Highest 500-3000 m/min

*Diamond loses hardness above 700°C and reacts with ferrous metals